Article and Picture Courtesy of http://www.enn.com/energy/article/30372

New Solar Panel Technology Stylish and Sustainable /energy/article/30372

The new cell technology combines nanoparticles and organic dyes that can be produced in any number of colors and designs.

The key component of the new modules is an organic dye which in combination with nanoparticles converts sunlight into electricity. Due to the small size of the nanoparticles, the modules are semi-transparent. This aspect makes them well suited for façade integration. The new solar cells are being developed by members of the Fraunhofer Institute for Solar Energy Systems ISE, who will be presenting their new technology in Tokyo at Nanotech 2008, the world’s largest trade fair for nanotechnology.

The solar module prototype is amber in color. It is possible, however, to produce the modules in other colors, or even to print images or text on the module so that it serves as a decorative element. These design options open up an entirely new range of possible applications. Instead of mounting the solar module on the roof of a building, the electricity producer could be integrated into windows. Used in this way, the new technology not only prohibits direct sunlight from entering the building interior but also generates electricity at the same time.

“We don’t see the dye solar cell as being a rival to the conventional silicon cell,” says Fraunhofer ISE physicist Andreas Hinsch. The module prototypes only achieve an efficiency of four percent, which is not sufficient for rooftop applications in comparison to the performance of crystalline silicon solar cells. On the other hand, dye solar cells have a clear advantage when it comes to façade integration.

The wafer-thin electricity-generating film, which lies between two glass panes, is produced from nanoparticles and applied using screen printing technique. This technique makes it possible to integrate any desired image on the module. A glass facade made of this material can be given a decorative and promotionally effective design, such as a colorful company logo, and delivers electricity into the bargain.

The dye solar module is still a prototype. The Fraunhofer researchers have developed it together with industry partners in the ColorSol project funded by the German Federal Ministry of Education and Research BMBF.

One particular challenge posed by the new technology is that the narrow gap between the two glass panes must be hermetically sealed so that no air can get in and destroy the reactive substances inside. The Fraunhofer experts have come up with a special solution to this problem. Instead of using polymeric glue like their competitors, they have decided to work with glass frit. To this end, glass powder is screen-printed onto the panes, and fuses with them at a temperature of around 600 degrees Celcius.

Fatigue tests under various weather conditions have shown that the solar cells still function properly even after several thousand hours. The long-term stability as such, however, has yet to be officially certified.

 
 

Article Courtesy of http://www.nytimes.com/2008/10/12/business/12stream.html?_r=1&emc=eta1&oref=slogin

Intuition + Money: An Aha Moment

By JOHN MARKOFF

Published: October 11, 2008

IT started with a Harvard physicist acting on a hunch. It ended up producing a new material, called black silicon, that could have a broad impact on technologies ranging from ultrasensitive sensors to photovoltaic cells.

 

Rick Friedman for The New York Times

James Carey, left, and Stephen Saylor of SiOnyx with black silicon wafers. Harvard plans to announce it has licensed patents for black silicon to the company.

On Monday, Harvard plans to announce that it has licensed patents for black silicon to SiOnyx, a company in Beverly, Mass., that has raised $11 million in venture financing.

This would never have happened if the physicist, Eric Mazur, and his graduate students had stuck to the original purpose of their research. He says their experience offers a lesson in government financing of science and technology, which is becoming so narrow and applied as to make discoveries like theirs much less likely.

A more narrow focus does have its advantages: for one, it can be more likely to produce an immediate payoff.

But in the current research environment, “you are less likely to be open to serendipity,” said Judith L. Estrin, an electrical engineer and author of “Closing the Innovation Gap: Reigniting the Spark of Creativity in a Global Economy” (McGraw-Hill, 2008).

Black silicon was discovered because Dr. Mazur started thinking outside the boundaries of the research he was doing in the late 1990s. His research group had been financed by the Army Research Organization to explore catalytic reactions on metallic surfaces.

“I got tired of metals and was worrying that my Army funding would dry up,” he said. “I wrote the new direction into a research proposal without thinking much about it — I just wrote it in; I don’t know why.” And even though there wasn’t an immediate practical application, he received the financing.

It was several years before he directed a graduate student to pursue his idea, which involved shining an exceptionally powerful laser light — briefly matching the energy produced by the sun falling on the surface of the entire earth — on a silicon wafer. On a hunch, the researcher also applied sulfur hexafluoride, a gas used by the semiconductor industry to make etchings for circuits.

The silicon wafer looked black to the naked eye. But when Dr. Mazur and his researchers examined the material with an electron microscope, they discovered that the surface was covered with a forest of ultra-tiny spikes.

At first, the researchers had no idea what they had stumbled onto, and that is typical of the way many scientific discoveries emerge. Cellophane, Teflon, Scotchgard and aspartame are among the many inventions that have emerged through some form of fortunate accident or intuition.

“In science, the most exciting expression isn’t ‘Eureka!’ It’s ‘Huh?’” said Michael Hawley, a computer scientist based in Cambridge, Mass., and a board member and investor in SiOnyx.

Black silicon has since been found to have extreme sensitivity to light. It is now on the verge of commercialization, most likely first in night vision systems.

“We have seen a 100 to 500 times increase in sensitivity to light compared to conventional silicon detectors,” said James Carey, a co-founder of SiOnyx who worked on the original experiments as a Harvard graduate student.

Dr. Mazur is an investor in SiOnyx and chairman of its scientific advisory board. As a result of his research, a number of academic and corporate research groups are still exploring the material, which absorbs about twice as much visible light as normal silicon and has the ability to detect infrared light that is invisible to the current generation of silicon detectors.

SiOnyx is already commercializing sensor-based chips as a technology development platform for other companies and for use in next-generation infrared imaging systems.

The new technology has a tremendous cost advantage in that it is compatible with current semiconductor manufacturing plants, according to Stephen Saylor, SiOnyx’s chief executive. It is certain to attract broad attention from a range of industries, including scientific and medical imaging markets.

In the future, the low cost and higher sensitivity of black silicon may also make it a contender in the multibillion-dollar digital camera and video markets, an area currently dominated by silicon and charge-coupled-device sensors.

SiOnyx is continuing to experiment with the photovoltaic properties of black silicon, but Mr. Saylor said the company had no plans to jump into the market to become a solar cell manufacturer. “Our engagement is going to be as a technology provider, not as a producer,” he said.

Instead, he is eager to get a new generation of supersensitive light detectors into the hands of entrepreneurs and experimenters who will be able to take the technology in unpredictable directions.

AND that is how this technology got to where it is today. To Dr. Mazur, that should be a lesson to technology funding agencies like the National Science Foundation and the Defense Advanced Research Projects Agency of the Pentagon.

“This is a very strong case in point for funding science for the advancement of science,” he said.

 

 

Article Courtesy of http://www.physorg.com/news144940463.html

Solar power game-changer: 'Near perfect' absorption of sunlight, from all angles

A new anti-reflective coating developed by researchers at Rensselaer Polytechnic Institute could help to overcome two major hurdles blocking the progress and wider use of solar power. The nanoengineered coating boosts the amount of sunlight captured by solar panels and allows those panels to absorb the entire spectrum of sunlight from any angle, regardless of the sun's position in the sky. Credit: Rensselaer/Shawn Lin

No matter which way you look at it, the notion of harvesting energy from the sun to power our homes and businesses is more absorbing than ever.

 

Researchers at Rensselaer Polytechnic Institute have discovered and demonstrated a new method for overcoming two major hurdles facing solar energy. By developing a new antireflective coating that boosts the amount of sunlight captured by solar panels and allows those panels to absorb the entire solar spectrum from nearly any angle, the research team has moved academia and industry closer to realizing high-efficiency, cost-effective solar power.

"To get maximum efficiency when converting solar power into electricity, you want a solar panel that can absorb nearly every single photon of light, regardless of the sun's position in the sky," said Shawn-Yu Lin, professor of physics at Rensselaer and a member of the university's Future Chips Constellation, who led the research project. "Our new antireflective coating makes this possible."

Results of the year-long project are explained in the paper "Realization of a Near Perfect Antireflection Coating for Silicon Solar Energy," published this week by the journal Optics Letters.

An untreated silicon solar cell only absorbs 67.4 percent of sunlight shone upon it — meaning that nearly one-third of that sunlight is reflected away and thus unharvestable. From an economic and efficiency perspective, this unharvested light is wasted potential and a major barrier hampering the proliferation and widespread adoption of solar power.

After a silicon surface was treated with Lin's new nanoengineered reflective coating, however, the material absorbed 96.21 percent of sunlight shone upon it — meaning that only 3.79 percent of the sunlight was reflected and unharvested. This huge gain in absorption was consistent across the entire spectrum of sunlight, from UV to visible light and infrared, and moves solar power a significant step forward toward economic viability.

Lin's new coating also successfully tackles the tricky challenge of angles.

Most surfaces and coatings are designed to absorb light — i.e., be antireflective — and transmit light — i.e., allow the light to pass through it — from a specific range of angles. Eyeglass lenses, for example, will absorb and transmit quite a bit of light from a light source directly in front of them, but those same lenses would absorb and transmit considerably less light if the light source were off to the side or on the wearer's periphery.

This same is true of conventional solar panels, which is why some industrial solar arrays are mechanized to slowly move throughout the day so their panels are perfectly aligned with the sun's position in the sky. Without this automated movement, the panels would not be optimally positioned and would therefore absorb less sunlight. The tradeoff for this increased efficiency, however, is the energy needed to power the automation system, the cost of upkeeping this system, and the possibility of errors or misalignment.

Lin's discovery could antiquate these automated solar arrays, as his antireflective coating absorbs sunlight evenly and equally from all angles. This means that a stationary solar panel treated with the coating would absorb 96.21 percent of sunlight no matter the position of the sun in the sky. So along with significantly better absorption of sunlight, Lin's discovery could also enable a new generation of stationary, more cost-efficient solar arrays.

"At the beginning of the project, we asked 'would it be possible to create a single antireflective structure that can work from all angles?' Then we attacked the problem from a fundamental perspective, tested and fine-tuned our theory, and created a working device," Lin said. Rensselaer physics graduate student Mei-Ling Kuo played a key role in the investigations.

Typical antireflective coatings are engineered to transmit light of one particular wavelength. Lin's new coating stacks seven of these layers, one on top of the other, in such a way that each layer enhances the antireflective properties of the layer below it. These additional layers also help to "bend" the flow of sunlight to an angle that augments the coating's antireflective properties. This means that each layer not only transmits sunlight, it also helps to capture any light that may have otherwise been reflected off of the layers below it.

The seven layers, each with a height of 50 nanometers to 100 nanometers, are made up of silicon dioxide and titanium dioxide nanorods positioned at an oblique angle — each layer looks and functions similar to a dense forest where sunlight is "captured" between the trees. The nanorods were attached to a silicon substrate via chemical vapor disposition, and Lin said the new coating can be affixed to nearly any photovoltaic materials for use in solar cells, including III-V multi-junction and cadmium telluride.

 

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